Lead-acid battery

From Academic Kids

Lead-acid batteries are the most commonly used rechargeable batteries today. They also represent the oldest design with one of the worst energy-to-weight ratios, although the power-to-weight ratio can be quite good. Also, the energy-to-volume ratio is good compared to other types of batteries. They are cheap and can supply high surge currents needed in starter motors. Every reasonably modern car uses a lead-acid battery for this purpose.

Lead-acid car batteries consist of six cells of 2 V nominal voltage. Each cell contains (in the charged state) electrodes of lead metal (Pb) and lead(IV) oxide (PbO2) in an electrolyte of about 37 % w/w sulfuric acid (H2SO4). Modern designs have gelified electrolytes. In the discharged state both electrodes turn into lead(II) sulfate and the electrolyte turns into water. (This is why discharged lead-acid batteries can freeze.)

Lead acid batteries for automotive use are not designed for deep discharge and should always be kept at maximum charge, using constant voltage at 13.8 V (for six element car batteries). Their capacity will severely suffer from deep cycling. Specially designed deep-cycle cells are much less susceptible to this problem, and are required for applications where the batteries are regularly discharged.

  • Quiescent(open-circuit) voltage at full battery: 12.6 V
  • Unloading-end voltage: 11.8 V
  • Charge with 13.2-14.4 V
  • Gasing voltage: 14.4 V
  • Continuous-preservation charge with max. 13.2 V
  • After full charge the terminal voltage will drop quickly to 13.2 V and then slowly to 12.6 V.

The energy to weight ratio, or specific energy, is in the range of 30 Wh/kg.

The chemical reactions are (charged to discharged):

Anode (oxidation): <math>\mbox{Pb}_{(s)}+\mbox{SO}_{4(aq)}^{2-} \leftrightarrow \mbox{PbSO}_{4(s)}+2e^-<math>

Cathode (reduction): <math>\mbox{PbO}_{2(s)}+\mbox{SO}_{4(aq)}^{2-}+4\mbox{H}^++2e^- \leftrightarrow \mbox{PbSO}_{4(s)}+2\mbox{H}_2\mbox{O}_{(l)}<math>

Because of the open cells with liquid electrolyte in most cheap car batteries, overcharging with excessive charging voltages will generate oxygen and hydrogen gas, forming an extremely explosive mix. This should be avoided. Caution must also be observed because of the extremely corrosive nature of sulphuric acid.

Automotive applications

A chemical compound in the form of tablets can be added to each cell to reduce sulfate build up, and improve battery condition, however the effectiveness of such treatments is subject to debate.

See Car battery

See also

ja:鉛蓄電池

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